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Fluorescence spectra of matrix isolated silver atoms

✍ Scribed by D.M. Kolb; D. Leutloff

Publisher: Elsevier Science
Year: 1978
Tongue: English
Weight: 361 KB
Volume: 55
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(78)87015-8

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✦ Synopsis

Sitvm atoms isolated in noble gas matrices show fiuorescence specta with large Stokes sfrifts, when optí&y excited via the SP ~5s transition which is three-fold splii in tfte matix by spin-orbit and crystal field uiteraction. The shirts afe explained by the fortnation ofan excïmerïc bond between tlxe excited metal atom and the notile gas ca&.. For Ag in Kr it is demonstrated, tfiat most of the Stokes shift arises from t&e grctund state reptdsion.

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