Spectra of porphyrins: XI. Absorption and fluorescence spectra of matrix isolated phthalocyanines
β Scribed by Larry Bajema; Martin Gouterman; Beat Meyer
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- English
- Weight
- 730 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0022-2852
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π SIMILAR VOLUMES
Sitvm atoms isolated in noble gas matrices show fiuorescence specta with large Stokes sfrifts, when optΓ&y excited via the SP ~5s transition which is three-fold splii in tfte matix by spin-orbit and crystal field uiteraction. The shirts afe explained by the fortnation ofan excΓ―merΓ―c bond between tlx
The fluorescence of Ni atoms isolated in NC. Ar, I(I and Xe matrices has been investigated, including time-resolved measurements. From an analysis of the emission spectra. a matrix shift for the 3ds4s2 3 the gas phase) with respect to rhe 3dg-Is' 3 F4 level (the gound state of Ni in D3 state was ded