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Crystal field effects in the optical spectra of matrix-isolated palladium atoms

✍ Scribed by W. Schrittenlacher; R. Grinter; W. Schroeder

Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
254 KB
Volume
128
Category
Article
ISSN
0009-2614

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✦ Synopsis

Slater-Condon calculation including a crystal field perturbation has been performed for Pd atoms. The optical spectrum of Pd in Ne is reproduced very well with this calculation, assuming a repulsive crystal field of 0, symmetry.

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Matrix effects on the fast atom bombardm
Matrix effects on the fast atom bombardment mass spectra of palladium complexes
✍ Larry M. Mallis; William J. Scott πŸ“‚ Article πŸ“… 1990 πŸ› John Wiley and Sons 🌐 English βš– 360 KB

In an attempt to identify and characterize the intermediates involved in multi-step palladium catalyzed coupling reactions, under fast atom bombardment (FAB) conditions, the selection of a matrix to enhance ion formation without degrading the palladium complex is critical. In general, it is observed