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Fluorescence lifetime and quenching rate measurements of the ultraviolet and visible emission bands of the CF3 radical

✍ Scribed by C.R. Quick Jr.; J.J. Tiee; J. Preses; R.E. Weston Jr.

Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 421 KB
Volume: 114
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(85)85101-0

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✦ Synopsis

Vacuum UV synchrotron radlatlon was used to produce electronically evclted CF3 radicals by photolysis of CFzCl, CF3Br, and CF31. The collrsion-free fluorescence hfetlme of both the UV and vlsrble etission bands of CFJ was measured to be 14-17 ns ask_:: a time-resolved photoncountmg detectlon system. The quenching rates of the UV and rwble band emlssmns by CF3 precursor molecules are (l-6) x 107 s-l Torr-'

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