## Reactions of 2-aryl-l,3-dithiolane-S-oxides 1 with MeMgI in refluxing benzene-ether furnish a useful procedure for introducing the isopropenyl group. The reaction may proceed via a fragmentation-coupling process leading to the alkylative olefination product.
FAB-Induced deprotonation, elimination and decomposition of 1,3-dithiolane S-oxides
โ Scribed by O. Bortolini; P. Traldi
- Book ID
- 112129519
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 1990
- Tongue
- English
- Weight
- 193 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0022-152X
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