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Decomposition of 3,6-dihydro-1,2-oxathiin 2-oxides to sulfur dioxide and 1,3-dienes. A .pi.4s+.pi.2s cycloreversion

✍ Scribed by Jung, F.; Molin, M.; Van der Elzen, R.; Durst, T.


Book ID
126477807
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
265 KB
Volume
96
Category
Article
ISSN
0002-7863

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The products of hetero-Diels Β± Alder reactions (sultines) and cheletropic addition reactions (sulfolenes) between 1,3-dienes and sulfur dioxide can be distinguished by their 17 O NMR shifts. Experimental data have been collected for derivatives of 3,6dihydro-1,2-oxathiin-2-oxide and of 2,5dihydrothi