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Elimination of neutral lithium atom from lithiated nucleobases upon collision-induced decomposition

✍ Scribed by K. P. Madhusudanan; S. B. Katti

Book ID: 101222604
Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 258 KB
Volume: 33
Category: Article
ISSN: 1076-5174
DOI: 10.1002/(sici)1096-9888(199801)33:1<20::aid-jms603>3.0.co;2-9

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✦ Synopsis

Lithium cationization of cytosine, thymine, adenine and guanine leads to the formation of multiply lithiated nucleobases. Upon collision-induced decomposition, these lithium complexes eliminate neutral lithium atom, presumably from species in which lithium has replaced the exchangeable hydrogens.

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