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Excitation-transfer studies of n2(a3σ+u) with s atoms and cs molecules

✍ Scribed by D.S. Richards; D.W. Setser


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
720 KB
Volume
136
Category
Article
ISSN
0009-2614

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✦ Synopsis


The excitation-transfer reaction N2(A 'Z: ) and CS molecules has been studied in a fast-flow reactor at 300 K; the excitation rate constant is (1.8';::) x10-l' cm3 molecule-' s-'. Excitation to the CS(a) state is favored over excitation to the Cs(a 'II) state. Excitation transfer from S( 'P) to S( 'S) is not a facile reaction and an upper limit to the rate constant is k( IS) 6 4x lo-i3 cm3 atom-' s-'


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