The reaction between N,(A3Zz, u'= 0) and SO(X 3x-) has been studied at room temperature\_ The total quenching rate constant is (1.2\*0.2)X10~'" cm3 molecule-' s-l and the SO(A3U) excitation rate constant is (OJf0.2)~10-'~ cm3 molecule-' s-'\_ Al&ough these rate constants have some absolute uncertain
Excitation-transfer studies of n2(a3σ+u) with s atoms and cs molecules
✍ Scribed by D.S. Richards; D.W. Setser
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 720 KB
- Volume
- 136
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
The excitation-transfer reaction N2(A 'Z: ) and CS molecules has been studied in a fast-flow reactor at 300 K; the excitation rate constant is (1.8';::) x10-l' cm3 molecule-' s-'. Excitation to the CS(a) state is favored over excitation to the Cs(a 'II) state. Excitation transfer from S( 'P) to S( 'S) is not a facile reaction and an upper limit to the rate constant is k( IS) 6 4x lo-i3 cm3 atom-' s-'
📜 SIMILAR VOLUMES
L@t rnoasurcments made during the afterglow oi pure nitrogen and helium-nitrogen mixtures indicate that mutual collisions of the N?(A 'XL) molecule are responsible for the formation of the Nz(C3n,) and Nz(C?nu) states. Results for the latter state arc in agreement with other workers. A value for th
A cw selcctivc laser excitation and fluoresccncc observation technique has been used to study rhe collicional eiecrronic excitation transfer process 7Li;(A 1 Cc, u', J') + Li(z 2s) -7Li2(X 1 r \_l, u",s' =S + 1) •t Li\*(Z2P) +AE for some sclectcd (v' = 17.6 < f < 30) rovibrational levels of Lig(A).
Emissio3 of+NO y-bands has been observed in a mixture IJ$N~ and NO. The results indicate the praduction of NS(A C,) in the resonance charge transfer reaction h2 NO-N2 + NO\* (y-band).