The collision-induced intramolecular energy transfer N2 (A '2: ) + M+N2 (B 'll,) + M was studied under molecular beam conditions using Xe and Nz as the collision partners. Specifically, the near-resonant transfer between the levels A, VI'= 1 O-B, u'= 2 was investigated by means of the product emissi
Production of N2(C3Πu) and N2(C′3Πu) by mutual collisions of N2(A3Σ+u) metastable molecules
✍ Scribed by G.N. Hays; C.J. Tracy; A.R. Demonchy; H.J. Oskam
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 352 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
L@t rnoasurcments made during the afterglow oi pure nitrogen and helium-nitrogen mixtures indicate that mutual collisions of the N?(A 'XL) molecule are responsible for the formation of the Nz(C3n,)
and Nz(C?nu) states. Results for the latter state arc in agreement with other workers. A value for the diffusion coefficient of the N2(A3&cu) state in helium is reported,
📜 SIMILAR VOLUMES
N2B3ng, Y = O-2 and N\*a"v;, Y = 0 were produced by pulsed rodiolysis af nitrogen (100-2000 torr) and fo!lowed by fast kinetic absorption spectroscopy in the second and fifth positive system. T!le rate constants for the denctivation of the species by nitrogen were found to be ~N~A,~ = 1.6i + 0.8; 2.
Quenching of N,(A3ZU+) by 0, 0, N, and