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The deactivation of N2B3Πg, ν = 0–2 and N2a′1Σ−u, ν = 0 by nitrogen

✍ Scribed by J.W. Dreyer; D. Perner

Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
371 KB
Volume
16
Category
Article
ISSN
0009-2614

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✦ Synopsis

N2B3ng, Y = O-2 and N*a"v;, Y = 0 were produced by pulsed rodiolysis af nitrogen (100-2000 torr) and fo!lowed by fast kinetic absorption spectroscopy in the second and fifth positive system. T!le rate constants for the denctivation of the species by nitrogen were found to be ~N~A,~ = 1.6i + 0.8; 2.25 i 0.2; 3.19 f 0.18 X IO-l2 cm3/sec for Y = 0, 1, 2 respectively and kN2a*,v=~ = (2.21 i 0.14) X IO-l3 cm3/sec.

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