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Quenching of N2(A3Σu+) by O2, O, N, and H

✍ Scribed by O. J. Dunn; R. A. Young


Publisher
John Wiley and Sons
Year
1976
Tongue
English
Weight
502 KB
Volume
8
Category
Article
ISSN
0538-8066

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✦ Synopsis


Quenching of N,(A3ZU+) by 0, 0, N, and


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Quenching of N2(A3Σ+u v=0) by H
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The rate constant for N,(A, v=O) deactivation by H has been measured by monitoring the decrease in the N,(A, v=O) -+N,(X, v=6) emission when H is added to a flow stream containing N\*(A). The value is found to be 5 x lo-" cm3 s-l, with an uncertainty of z 50%.

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The quenching re.ac!ions 01 memsmble niwogcn molecuks I$(A%. u = 0. I. 2) by 02 has been sludisd in a rrmperamrscontrolled flowing afterglow experimenl. The rexlion tale constants at 300 K are 2.5 X IO-"\_ 4.0X IO-" and 4.5 X lo-" c&/s molecule for u = 0. 1 and 2, respectively. They vary as Z"' m th

Rate constant for the deactivation of O2
✍ R.D. Kenner; E.A. Ogryzlo 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 301 KB

A vaIue of (9.3 = 1.7) X IO-\*\* cm3 molecule-' s-' has been determined as the rate constant for the quenchinp ai Op(A 3ZG) by N2 at 25OC.