molecules from a discharge have been analyzed by the emission of the infrared atmospheric (0.0) bancfat 12700 A and by the emission of the atmospheric (0,O) band at 7619 A due to the energy pooling reaction ## 202(1Agj -+02('Cs) + 02(%;) . Particular rate constants for the deactivation of 02(1 A
Quenching reactions of metastable N2(A 3Σ, υ= 0, 1, 2) molecules by O2
✍ Scribed by A.R. de Sousa; M. Touzeau; M. Petitdidier
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 423 KB
- Volume
- 121
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
The quenching re.ac!ions 01 memsmble niwogcn molecuks I$(A%. u = 0. I. 2) by 02 has been sludisd in a rrmperamrscontrolled flowing afterglow experimenl. The rexlion tale constants at 300 K are 2.5 X IO-"_ 4.0X IO-" and 4.5 X lo-" c&/s molecule for u = 0. 1 and 2, respectively. They vary as Z"' m the lemperarure range 80-300 K for u = 1. 2 and in Ihe range 80-560 K for u = 0. The branching ralio or this reaction leading LO N,O production is round IO be 1 i 1% and is compared with previous results.
📜 SIMILAR VOLUMES
Singlet molecular oxygen, 02('Z,i), is one of the irqportant intermediate species in the atmospheres of Earth, Mars, and Venus. To elucidate the chemistry of this excited molecular oxygen, a series of kinetic measurements have been undertaken using the flow-dischargeioptical-emission technique. By m
Quenching of N,(A3ZU+) by 0, 0, N, and
The rate constant for N,(A, v=O) deactivation by H has been measured by monitoring the decrease in the N,(A, v=O) -+N,(X, v=6) emission when H is added to a flow stream containing N\*(A). The value is found to be 5 x lo-" cm3 s-l, with an uncertainty of z 50%.