✦ LIBER ✦

Rate constant for the deactivation of O2 (A3Σu+ by N2

✍ Scribed by R.D. Kenner; E.A. Ogryzlo

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 301 KB
Volume: 103
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(83)80383-2

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✦ Synopsis

A vaIue of (9.3 = 1.7) X IO-** cm3 molecule-' s-' has been determined as the rate constant for the quenchinp ai Op(A 3ZG) by N2 at 25OC.

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Rate constants for the reaction O(3p)+ O3 (IAI) --, 202 (X 32g ) are reported using variational transition state theory. A semi-empirical potential energy surface based on a double many-body expansion method due to Varandas and Pais is used to obtain transition state information. The computed rate c