Relaxation rates for 02('&+) by nonradiative pathways have been determined using the fast-flow technique. 02 ('\3,+) is formed from 0 2 ( l A g ! by an energy pooling process. 02('AK) is generated by passing purified oxygen through a microwave discharge. Oxygen atoms are removed by distilling mercur
Deactivation of O2(A3Σ) by O2, O, and Ar
✍ Scribed by R. D. Kenner; E. A. Ogryzlo
- Publisher
- John Wiley and Sons
- Year
- 1980
- Tongue
- English
- Weight
- 379 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0538-8066
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✦ Synopsis
0 2 in the A38: state has been prepared in a discharge flow system by recombining oxygen atoms on a nickel surface. The decay of this excited state was followed by observing the emission between 280 and 400 nm. The wall deactivation was observed to approach unit efficiency. Rate constants were determined to be 0.9 X 2.9 X and 8.6 X cm3/molecule sec for the quenching of Oz(A3ZZ:) by O,Oz, and Ar, respectively.
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