The lime decay of N,(AjI: ) produced by pulsed phololysls of GIN, a1 193 nm erhlblls I~O componenls a fasi decay correspondmg IO pseudo-firsl-order quenchmg by GIN, and a much slouer decal correspondmg IO a chain process In which N?(A'Z; ) IS regenerated The iale conslanl for N,(A'T; ) qurnchng by
Radiation and quenching of the A 3Σu+ triplet excitation in solid N2
✍ Scribed by G. Zumofen; J. Sedlacek
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 226 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0022-2860
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Quenching of N,(A3ZU+) by 0, 0, N, and
The reaction between N,(A3Zz, u'= 0) and SO(X 3x-) has been studied at room temperature\_ The total quenching rate constant is (1.2\*0.2)X10~'" cm3 molecule-' s-l and the SO(A3U) excitation rate constant is (OJf0.2)~10-'~ cm3 molecule-' s-'\_ Al&ough these rate constants have some absolute uncertain
The excitation-transfer reaction N2(A 'Z: ) and CS molecules has been studied in a fast-flow reactor at 300 K; the excitation rate constant is (1.8';::) x10-l' cm3 molecule-' s-'. Excitation to the CS(a) state is favored over excitation to the Cs(a 'II) state. Excitation transfer from S( 'P) to S( '