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Excitation-transfer reaction of N2(A 3Σu+) with SO(X 3Σ−) and S2(X 3Σg−) and quenching rate constants of some sulfur- and halogen-containing molecules

✍ Scribed by De-Zhao Cao; D.W. Setser

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
674 KB
Volume
116
Category
Article
ISSN
0009-2614

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✦ Synopsis

The reaction between N,(A3Zz, u'= 0) and SO(X 3x-) has been studied at room temperature_ The total quenching rate constant is (1.2*0.2)X10~'" cm3 molecule-' s-l and the SO(A3U) excitation rate constant is (OJf0.2)~10-'~ cm3 molecule-' s-'_ Al&ough these rate constants have some absolute uncertainty because of the diffkuhy of measuring (SO], the SO+ N,(A) excitation-transfer reaction appears to be an efficient system for utilizing the energy of the metastable N,(A) state. Less extensive results also are presented for excitation transfer between N,(A) and s(X). The totat quenching rate constant is z 6x10-1'

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