Ethylenediammonium tetrathiotungstate(VI)
✍ Scribed by Srinivasan, Bikshandarkoil R. ;Dhuri, Sunder N. ;Näther, Christian ;Bensch, Wolfgang
- Publisher
- International Union of Crystallography
- Year
- 2002
- Tongue
- English
- Weight
- 295 KB
- Volume
- 58
- Category
- Article
- ISSN
- 1600-5368
No coin nor oath required. For personal study only.
✦ Synopsis
The structure of the title complex, (C 2 H 10 N 2 )[WS 4 ], consists of tetrahedral [WS 4 ] 2À anions which are connected to the organic ethylenediammonium dications via hydrogen bonding. All atoms are located in general positions.
📜 SIMILAR VOLUMES
The title compound, (C 3 H 12 N 2 )[CdI 4 ] [abbreviated (MEDA)-CdI 4 ], contains isolated N-methylethylenediammonium cations and tetrahedral tetraiodidecadmate(II) anions, forming segregated layers. Hydrogen bonding between cations and anions provides three-dimensional stability to the crystal stru
Single-crystal X-ray study T = 150 K Mean '(W±S) = 0.001 A Ê R factor = 0.018 wR factor = 0.048 Data-to-parameter ratio = 25.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The structure of the title complex, (CNH~6~)~2~[MoS~4~], consists of tetrahedral tetrathiomolybdate dianions, [MoS~4~]^2−^, and two crystallographically independent methylammonium cations, MeNH~3~ ^+^, all of which are located on mirror planes. The tetrathiomolybdate anions are linked to the organic