The structure of the title complex, (C 2 H 10 N 2 )[WS 4 ], consists of tetrahedral [WS 4 ] 2À anions which are connected to the organic ethylenediammonium dications via hydrogen bonding. All atoms are located in general positions.
Ethylenediammonium disulfidodecamolybdate(VI)
✍ Scribed by Sun, Qiaozhen ;Zhang, Hanhui ;Huang, Changcang ;Sun, Ruiqing ;Wang, Yongjing
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 264 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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The title compound, (C 3 H 12 N 2 )[CdI 4 ] [abbreviated (MEDA)-CdI 4 ], contains isolated N-methylethylenediammonium cations and tetrahedral tetraiodidecadmate(II) anions, forming segregated layers. Hydrogen bonding between cations and anions provides three-dimensional stability to the crystal stru
Single-crystal X-ray study T = 295 K Mean '(C±C) = 0.003 A Ê R factor = 0.044 wR factor = 0.143 Data-to-parameter ratio = 14.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.