𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Bis(methyl­ammonium) tetra­thio­molybdate(VI)

✍ Scribed by Srinivasan, Bikshandarkoil R. ;Näther, Christian ;Naik, Ashish R. ;Bensch, Wolfgang

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
287 KB
Volume
62
Category
Article
ISSN
1600-5368

No coin nor oath required. For personal study only.

✦ Synopsis

The structure of the title complex, (CNH~6~)~2~[MoS~4~], consists of tetrahedral tetrathiomolybdate dianions, [MoS~4~]^2−^, and two crystallographically independent methylammonium cations, MeNH~3~
^+^, all of which are located on mirror planes. The tetrathiomolybdate anions are linked to the organic cations via hydrogen bonding.

📜 SIMILAR VOLUMES

Butane-1,4-diammonium tetra­thio­molybda
Butane-1,4-diammonium tetra­thio­molybdate(VI)
✍ Srinivasan, Bikshandarkoil R. ;Näther, Christian ;Bensch, Wolfgang 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 85 KB
Ethyl­enedi­ammonium tetra­thio­tungstat
Ethyl­enedi­ammonium tetra­thio­tungstate(VI)
✍ Srinivasan, Bikshandarkoil R. ;Dhuri, Sunder N. ;Näther, Christian ;Bensch, Wolf 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 295 KB

The structure of the title complex, (C 2 H 10 N 2 )[WS 4 ], consists of tetrahedral [WS 4 ] 2À anions which are connected to the organic ethylenediammonium dications via hydrogen bonding. All atoms are located in general positions.

Bis­(tetra­methyl­ammonium) hexa­aqua­co
Bis­(tetra­methyl­ammonium) hexa­aqua­cobalt(II) β-octamolybdate(VI)
✍ Chen, Shu-Mei ;Lu, Can-Zhong ;Yu, Ya-Qin ;Zhang, Quan-Zheng ;He, Xiang 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 139 KB

The title compound, (C 4 H 12 N) 2 [Co(H 2 O) 6 ][±Mo 8 O 26 ], contains -octamolybdate ([-Mo 8 O 26 ] 4À ), tetramethylammonium and [Co(H 2 O) 6 ] 2+ ions. The [-Mo 8 O 26 ] 4À anion and [Co(H 2 O) 6 ] 2+ cations lie on inversion centers, and the tetramethylammonium cations lie on twofold rotation