1,4-Dimethylpiperazinium tetrathiotungstate(VI)
✍ Scribed by Srinivasan, Bikshandarkoil R. ;Dhuri, Sunder N. ;Näther, Christian ;Bensch, Wolfgang
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 291 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 150 K Mean '(W±S) = 0.001 A Ê R factor = 0.018 wR factor = 0.048 Data-to-parameter ratio = 25.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The structure of the title complex, (C 2 H 10 N 2 )[WS 4 ], consists of tetrahedral [WS 4 ] 2À anions which are connected to the organic ethylenediammonium dications via hydrogen bonding. All atoms are located in general positions.
Tetramethyltetrathiafulvalene and 1,4-dinitrobenzene co-crystallize in a mixed-stack 1:1 complex, C 10 H 12 S 4 ÁC 6 H 4 N 2 O 4 , without appreciable charge transfer. Both molecules lie on the same crystallographic twofold axis.