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Enantioselective Synthesis of the [6,6] Spiroketal Core of Reveromycin A

✍ Scribed by Drouet, Keith E.; Ling, Taotao; Tran, Hung V.; Theodorakis, Emmanuel A.

Book ID
127320987
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
92 KB
Volume
2
Category
Article
ISSN
1523-7060

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πŸ“œ SIMILAR VOLUMES

ChemInform Abstract: Enantioselective Sy
ChemInform Abstract: Enantioselective Synthesis of the [6,6] Spiroketal Core (I) of Reveromycin A (II).
✍ Keith E. Drouet; Taotao Ling; Hung V. Tran; Emmanuel A. Theodorakis πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 26 KB πŸ‘ 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v

Hetero-Diels–Alder synthesis of the spir
Hetero-Diels–Alder synthesis of the spiroketal fragment of reveromycin A
✍ Mariana El Sous; Mark A Rizzacasa πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 132 KB

The asymmetric synthesis of the 6,6-spiroketal fragment 15 of the epidermal growth factor inhibitor reveromycin A (1) is described. A hetero-Diels-Alder reaction was utilized to construct the 6,6-spiroketal 14 and subsequent stereoselective hydroboration provided reveromycin A spiroketal 15.

Synthetic studies on reveromycin A: Ster
Synthetic studies on reveromycin A: Stereoselective synthesis of the spiroketal system
✍ Takeshi Shimizu; Ryoichi Kobayashi; Katsuhisa Osako; Hiroyuki Osada; Ta-i Nakata πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 French βš– 228 KB

The 6,6-spiroketal system of reveromycin A (1), corresponding to the C9-C20 part, was Slm'eoseleetively synthesized and the absolute configuration at Cll, C12, C15, C18 and C19 of I was confirmed by the synthesis of the 5,6-spiroketal derivative degradated from 1.