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Synthetic studies on reveromycin A: Stereoselective synthesis of the spiroketal system

✍ Scribed by Takeshi Shimizu; Ryoichi Kobayashi; Katsuhisa Osako; Hiroyuki Osada; Ta-i Nakata

Publisher: Elsevier Science
Year: 1996
Tongue: French
Weight: 228 KB
Volume: 37
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(96)01460-8

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✦ Synopsis

The 6,6-spiroketal system of reveromycin A (1), corresponding to the C9-C20 part, was Slm'eoseleetively synthesized and the absolute configuration at Cll, C12, C15, C18 and C19 of I was confirmed by the synthesis of the 5,6-spiroketal derivative degradated from 1.

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