Electroorganic chemistry. 118. Electroreductive intermolecular coupling of ketones with olefins
โ Scribed by Shono, Tatsuya; Kashimura, Shigenori; Mori, Yasuo; Hayashi, Takashi; Soejima, Takeshi; Yamaguchi, Yoshihide
- Book ID
- 127274793
- Publisher
- American Chemical Society
- Year
- 1989
- Tongue
- English
- Weight
- 343 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0022-3263
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Electroorganic Chemistry. Part 155. Electroreductive Coupling of Aliphatic Amides. A Useful Method for the Synthesis of ฮฑ-Amino Ketones. -Cathodic reduction of aliphatic amides (I) in the presence of trimethylsilyl chloride (II) using magnesium electrodes is described. The enol ether coupling produ
The electroreduction of ketones together with O-methyl oximes gave intermolecularly coupled products, 2-methoxyamino alcohols, which were easily reduced to 2-amino alcohols. Reductive cross coupling of C=O group with C=N group will provide a convenient route to the synthesis of 2amino alcohols (eql