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Electroreductive intermolecular coupling of ketones with O-methyl oximes. A convenient route to synthesis of 2-amino alcohols

✍ Scribed by Tatsuya Shono; Naoki Kise; Taku Fujimoto

Publisher: Elsevier Science
Year: 1991
Tongue: French
Weight: 243 KB
Volume: 32
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)79486-x

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✦ Synopsis

The electroreduction of ketones together with O-methyl oximes gave intermolecularly coupled products, 2-methoxyamino alcohols, which were easily reduced to 2-amino alcohols.

Reductive cross coupling of C=O group with C=N group will provide a convenient route to the synthesis of 2amino alcohols (eql). It has been reported that electroreductive coupling of N-methylbenzylideneaine with 'C' 'c' ::

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