Cathodic coupling of ketones with trimet
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Shigenori Kashimura; Manabu Ishifune; Yoshihiro Murai; Tatsuya Shono
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Article
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1996
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Elsevier Science
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French
โ 225 KB
Cathodic coupling of ketones with 3-(trimethylsilyl)allyl alcohols has been found to give trimethylsilyl substituted 1,3-diols with high diastereoselectivity, whereas that with 2-(trimethylsilyl)allyl alcohols afforded homoallylic alcohols through the Peterson elimination of intermediately formed tr