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ChemInform Abstract: Electroorganic Chemistry. Part 151. Cathodic Coupling of Ketones with Trimethylsilyl Substituted Allyl Alcohols.

โœ Scribed by S. KASHIMURA; M. ISHIFUNE; Y. MURAI; T. SHONO


Book ID
112041606
Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
27
Category
Article
ISSN
0931-7597

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Cathodic coupling of ketones with trimet
โœ Shigenori Kashimura; Manabu Ishifune; Yoshihiro Murai; Tatsuya Shono ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 225 KB

Cathodic coupling of ketones with 3-(trimethylsilyl)allyl alcohols has been found to give trimethylsilyl substituted 1,3-diols with high diastereoselectivity, whereas that with 2-(trimethylsilyl)allyl alcohols afforded homoallylic alcohols through the Peterson elimination of intermediately formed tr