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Electroreductive Intermolecular Coupling of 3-Methoxycarbonylindoles with Ketones

โœ Scribed by Kise, Naoki; Sueyoshi, Akinori; Takeuchi, Shin-ichirou; Sakurai, Toshihiko


Book ID
120337888
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
438 KB
Volume
15
Category
Article
ISSN
1523-7060

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Electroreductive intermolecular coupling
โœ Tatsuya Shono; Naoki Kise; Taku Fujimoto ๐Ÿ“‚ Article ๐Ÿ“… 1991 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 243 KB

The electroreduction of ketones together with O-methyl oximes gave intermolecularly coupled products, 2-methoxyamino alcohols, which were easily reduced to 2-amino alcohols. Reductive cross coupling of C=O group with C=N group will provide a convenient route to the synthesis of 2amino alcohols (eql