The molecule of the title compound, C 15 H 15 NO 2 , is not planar, displaying a dihedral angle of 21.21 (18) between the two aromatic rings. The central N C bond distance of 1.279 (4) A is typical for an imine double bond. There are intramolecular O-HÁ Á ÁN and intermolecular O-HÁ Á ÁO hydrogen bon
(E)-2-[4-(Dimethylamino)phenyliminomethyl]-6-methylphenol
✍ Scribed by Gül, Zarife Sibel ;Erşahin, Ferda ;Ağar, Erbil ;Işık, Şamil
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 353 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, C 16 H 18 N 2 O, a Schiff base, crystallizes in the phenol-imine tautomeric form, with a strong intramolecular O-HÁ Á ÁN hydrogen bond which forms an almost planar ring.
📜 SIMILAR VOLUMES
The molecule of the title compound, C 15 H 12 F 3 NO, is not planar and the dihedral angle between the planes of the two aromatic rings is 33.82 (11) . The molecule exists in the phenol-imine tautomeric form, with a strong intramolecular O-HÁ Á ÁN hydrogen bond [NÁ Á ÁO = 2.609 (3) A ˚]. ## Related
The title compound, C 17 H 19 NO 4 , was synthesized by the Stobbe condensation reaction of p-dimethylaminobenzaldehyde and diethyl succinate, followed by cyclization of the Stobbe product. The crystal structure is stabilized by intermolecular C-HÁ Á Á interactions.