(E)-2-[(3-Bromophenylimino)methyl]-6-methylphenol
✍ Scribed by Akkaya, Abdullah ;Erşahin, Ferda ;Şenel, İsmet ;Ağar, Erb˙il ;Büyükgüngör, Orhan
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 240 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The molecule of the title compound, C 15 H 15 NO 2 , is not planar, displaying a dihedral angle of 21.21 (18) between the two aromatic rings. The central N C bond distance of 1.279 (4) A is typical for an imine double bond. There are intramolecular O-HÁ Á ÁN and intermolecular O-HÁ Á ÁO hydrogen bon
The title compound, C 16 H 18 N 2 O, a Schiff base, crystallizes in the phenol-imine tautomeric form, with a strong intramolecular O-HÁ Á ÁN hydrogen bond which forms an almost planar ring.
Single-crystal X-ray study T = 213 K Mean '(C±C) = 0.005 A Ê R factor = 0.062 wR factor = 0.148 Data-to-parameter ratio = 13.1 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the molecule of the title compound, C 15 H 13 ClN 2 O 4 , the pyrimidine and benzene rings form a dihedral angle of 69.3 (3) . Nostacking interactions are observed in the crystal structure.