The title compound, C 16 H 18 N 2 O, a Schiff base, crystallizes in the phenol-imine tautomeric form, with a strong intramolecular O-HÁ Á ÁN hydrogen bond which forms an almost planar ring.
(E)-2-[2-(Hydroxymethyl)phenyliminomethyl]-6-methylphenol
✍ Scribed by Gül, Zarife Sibel ;Erşahin, Ferda ;Ağar, Erbil ;Işık, Şamil
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 975 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The molecule of the title compound, C 15 H 15 NO 2 , is not planar, displaying a dihedral angle of 21.21 (18) between the two aromatic rings. The central N C bond distance of 1.279 (4) A is typical for an imine double bond. There are intramolecular O-HÁ Á ÁN and intermolecular O-HÁ Á ÁO hydrogen bonds.
📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê Disorder in main residue R factor = 0.044 wR factor = 0.108 Data-to-parameter ratio = 15.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [Co(C 14 H 12 NO 2 ) 2 ]NO 3 ÁH 2 O, is the first structurally characterized mononuclear complex of the monoanionic tridentate N-(2-hydroxymethylphenyl)salycylideneiminate ligand. The Co atom has an octahedral environment formed by two ligands with meridional coordination. metal-