A dinuclear nickel(II) complex of the ligand 2,6-bis[2-(dimethylamino)ethyliminomethyl]-4-methylphenol
✍ Scribed by Adams, Harry ;Clunas, Scott ;Fenton, David E.
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 207 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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## Abstract The ligand α,α′‐bis{bis[1‐(1′‐methyl‐2′‐benzimidazolyl)methyl]amino}‐__m__‐xylene (L‐55) forms the complexes [Cu^I^~2~(L‐55)(MeCN)~2~](PF~6~)~2~ (1) and [Cu^II^~2~(L‐55)(OMe)~2~][ClO~4~]~2~ (2), in which an extremely weak axial amine interaction is imposed by the small five‐membered ben
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.014 A Ê R factor = 0.097 wR factor = 0.199 Data-to-parameter ratio = 13.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Single-crystal X-ray study T = 153 K Mean '(C±C) = 0.005 A Ê R factor = 0.029 wR factor = 0.060 Data-to-parameter ratio = 11.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.