Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.08 A Ê R factor = 0.056 wR factor = 0.161 Data-to-parameter ratio = 13.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
A dinuclear Schiff base iron(III) complex with the ligand N,N′-bis(2-oxidophenylmethyleneimino)propane-1,2-diamine
✍ Scribed by You, Zhong-Lu ;Zhu, Hai-Liang
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 355 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
As an extension of our work on the structural characterization of Schiff base complexes, the title mononuclear iron(III) complex, (I), is reported here. Compound (I) is an electronically neutral mononuclear iron(III) compound (Fig. 1). The Fe III atom has a slightly distorted octahedral geometry an
Strictly speakmg, the symmetry of the FeOe chromophore is below axial and a rhombic zero field splitting parameter E should be introduced in the spin Hamiltonian. In other respects, the intermolecular interactions, that we did not take into account, are most probably very weak owing to the large sep
## Abstract The ligand __N,N′__‐bis(6‐methyl‐2‐pyridylmethyl)‐__N,N′__‐bis(2‐pyridylmethyl)ethane‐1,2‐diamine (L~6~^2^2M) has allowed to prepare the new Fe^II^ complex [(L~6~^2^2M)FeCl~2~] (1), and to compare its structural and spectroscopic characteristics with [(L~6~^2^2M)FeCl]PF~6~ (2). The mole
## Abstract Two neutral complexes [(L~6~^3^4M)Fe~2~Cl~4~]·2H~2~O·2CHCl~3~ (1) and [(L~6~^3^4M)Mn~2~Cl~4~]·CH~3~CN (2) have been synthesized {L~6~^3^4M = __N__,__N__,__N′__,__N′__‐tetrakis[(6‐methyl‐2‐pyridyl)methyl]propane‐1,3‐diamine} and their molecular structures established by X‐ray crystallogr