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Aqua­[N,N′-bis(2-oxido­phenyl­methyl­ene­imino)-1,3-di­amino­propane](thio­cyanato)­iron(III)

✍ Scribed by You, Zhong-Lu ;Zhu, Hai-Liang ;Liu, Wei-Sheng

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
442 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

As an extension of our work on the structural characterization of Schiff base complexes, the title mononuclear iron(III) complex, (I), is reported here.

Compound (I) is an electronically neutral mononuclear iron(III) compound (Fig. 1). The Fe III atom has a slightly distorted octahedral geometry and is coordinated by one Schiff base ligand L [L is the N,N H -bis(2-hydroxyphenylmethyleneimino)-1,3-diaminopropane anion], one thiocyanate anion and one water molecule. The Schiff base ligand L acts as

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