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Aqua­bis(1,5-di­methyl-2-phenyl-4-{[(E)-4-pyridyl­methyl­ene-κN]­amino}pyrazolidin-3-one)­dinitratonickel(II)

✍ Scribed by Liang, Hong ;Wang, Xian-Wen ;Chen, Zhen-Feng ;Huang, Ling ;Zou, Hong-Li ;Zhou, Jian ;Yu, Kai-Bei


Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
288 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title compound, [Ni(NO 3 ) 2 (C 17 H 16 N 4 O) 2 (H 2 O)], the six-coordinate Ni atom is bound by two trans 4-aminoantipyrine ligands. Such compounds possess antimicrobial properties. The crystal packing is stabilized by intermolecular hydrogen bonds and non-classical CÐHÁ Á ÁO hydrogen bonds, which generate a three-dimensional network.


📜 SIMILAR VOLUMES


Di­aqua­dibenzoatobis­[2-(4-pyridyl-κN)-
✍ Zhao, Qihua ;Wang, Xiaofeng ;Fang, Ruibin ;Tiekink, Edward R. T. 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 410 KB

Single-crystal X-ray study T = 223 K Mean '(C±C) = 0.003 A Ê R factor = 0.049 wR factor = 0.123 Data-to-parameter ratio = 21.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

Bis{5-methyl-4-[(Z)-(1-naphthyl­amino)­p
✍ Lü, Xing-Qiang ;Bao, Feng ;Wu, Qing ;Kang, Bei-Sheng ;Ng, Seik Weng 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 225 KB

In the title complex, [Ag(C 27 H 21 N 3 O) 2 ]PF 6 , the Ag atom occupies a centre of symmetry, resulting in linear NÐAgÐN coordination [AgÐN = 2.124 (2) A Ê ]. The P atom of the counter-anion has 1 site symmetry.