phenylmethylene]-1H-pyrazol-3(4H)-onato-jO}cobalt(II)
Aquabis(1,5-dimethyl-2-phenyl-4-{[(E)-4-pyridylmethylene-κN]amino}pyrazolidin-3-one)dinitratonickel(II)
✍ Scribed by Liang, Hong ;Wang, Xian-Wen ;Chen, Zhen-Feng ;Huang, Ling ;Zou, Hong-Li ;Zhou, Jian ;Yu, Kai-Bei
- Publisher
- International Union of Crystallography
- Year
- 2004
- Tongue
- English
- Weight
- 288 KB
- Volume
- 60
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, [Ni(NO 3 ) 2 (C 17 H 16 N 4 O) 2 (H 2 O)], the six-coordinate Ni atom is bound by two trans 4-aminoantipyrine ligands. Such compounds possess antimicrobial properties. The crystal packing is stabilized by intermolecular hydrogen bonds and non-classical CÐHÁ Á ÁO hydrogen bonds, which generate a three-dimensional network.
📜 SIMILAR VOLUMES
Bis{4-[(Z)-(2,4-dimethylphenylamino)phenylmethylene]-3-methyl-1-phenyl-1H-pyrazol-5(4H)-onato-j 2 N,O}(ethanol-jO)nickel(II)
Single-crystal X-ray study T = 223 K Mean '(C±C) = 0.003 A Ê R factor = 0.049 wR factor = 0.123 Data-to-parameter ratio = 21.4 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
In the title complex, [Ag(C 27 H 21 N 3 O) 2 ]PF 6 , the Ag atom occupies a centre of symmetry, resulting in linear NÐAgÐN coordination [AgÐN = 2.124 (2) A Ê ]. The P atom of the counter-anion has 1 site symmetry.