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Bis{5-methyl-4-[(Z)-(1-naphthyl­amino)­phenyl­methyl­ene]-2-phenyl-3H-pyrazol-3-one-κ2N,N′}silver(I) hexa­fluoro­phosphate

✍ Scribed by Lü, Xing-Qiang ;Bao, Feng ;Wu, Qing ;Kang, Bei-Sheng ;Ng, Seik Weng

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
225 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title complex, [Ag(C 27 H 21 N 3 O) 2 ]PF 6 , the Ag atom occupies a centre of symmetry, resulting in linear NÐAgÐN coordination [AgÐN = 2.124 (2) A Ê ]. The P atom of the counter-anion has 1 site symmetry.

📜 SIMILAR VOLUMES

5-Methyl-2-phenyl-4-[(Z)-(2-tolyl­amino)
5-Methyl-2-phenyl-4-[(Z)-(2-tolyl­amino)­phenyl­methyl­ene]­pyrazol-3(2H)-one
✍ Bao, Feng ;Lü, Xingqiang ;Wu, Qing ;Kang, Beisheng ;Ng, Seik Weng 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 186 KB

The NH unit on the exocyclic C C double bond in the title compound, C 24 H 21 N 3 O, lies on the same side of the double bond as the carbonyl unit of the pyrazolone ring, and the two interact through an NÐHÁ Á ÁO hydrogen bond [2.695 (2) A Ê ].

4-[(Z)-(2-Fluorenyl­amino)­phenyl­methyl
4-[(Z)-(2-Fluorenyl­amino)­phenyl­methyl­ene]-5-methyl-2-phenyl-2H-pyrazol-3(4H)-one
✍ Bao, Feng ;Lü, Xing-Qiang ;Wu, Qing ;Ng, Seik Weng 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 176 KB

The NH unit on the exocyclic C C double bond in the title compound, C 30 H 23 N 3 O, lies on the same side of the double bond as the carbonyl unit of the pyrazolonyl ring, and the two interact through an NÐHÁ Á ÁO hydrogen bond [2.671 (2) A Ê ].