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Domino Catalysis: Palladium-Catalyzed Carbonylation of Allylic Alcohols to β,γ-Unsaturated Esters

✍ Scribed by Liu, Qiang; Wu, Lipeng; Jiao, Haijun; Fang, Xianjie; Jackstell, Ralf; Beller, Matthias


Book ID
120475086
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
646 KB
Volume
52
Category
Article
ISSN
0044-8249

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Palladium clay catalyzed regio- and ster
✍ Ruth Naigre; Howard Alper 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 434 KB

Palladium acetate immobilized on montmorillonite is an effective catalyst for the carbonylation of secondary allylic alcohols with carbon monoxide, in the presence of triphenylphosphine and an acid promoter, affording P,y-unsaturated acids in 39-56% isolated yields. The reaction is regio-and stereos