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Palladium-catalyzed decarboxylation-carbonylation of allylic carbonates to give β,γ-unsaturated esters under mild conditions

✍ Scribed by Jiro Tsuji; Koji Sato; Hiroshi Okumoto

Publisher: Elsevier Science
Year: 1982
Tongue: French
Weight: 111 KB
Volume: 23
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)85793-7

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✦ Synopsis

Allyllc carbonates undergo facile palladium-catalyzed decarboxylatloncarbonylatlon under mild conditions to give 6,-y-unsaturated esters in high yields using palladium-phosphlne complex as a catalyst.

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