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Palladium clay catalyzed regio- and stereospecific synthesis of β,γ-unsaturated acids by the carbonylation of allylic alcohols

✍ Scribed by Ruth Naigre; Howard Alper

Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
434 KB
Volume
111
Category
Article
ISSN
1381-1169

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✦ Synopsis

Palladium acetate immobilized on montmorillonite is an effective catalyst for the carbonylation of secondary allylic alcohols with carbon monoxide, in the presence of triphenylphosphine and an acid promoter, affording P,y-unsaturated acids in 39-56% isolated yields. The reaction is regio-and stereospecific.

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