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Diphenylmethylsilyl ether (DPMS): a protecting group for alcohols

โœ Scribed by Denmark, Scott E.; Hammer, Robert P.; Weber, Eric J.; Habermas, Karl L.


Book ID
121184507
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
559 KB
Volume
52
Category
Article
ISSN
0022-3263

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The diethylisopropylsilyl group: A new p
โœ Kazunobu Toshima; Satsuki Mukaiyama; Mitsuhiro Kinoshita; Kuniaki Tatsuta ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 167 KB

The diethylisopropylsilyl (DEIPS) group which is a new protective group for alcohols has been first characterized. DEIPS group can be distinguished from t-butyldimethylsilyl, triethylsilyl, tetrahydropyranyl groups and 2-deoxy glycoside with high selectivity in removing under mild acidic condition,