๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

The Trimethylsilyl Xylyl (TIX) Ether: A Useful Protecting Group for Alcohols.

โœ Scribed by Ch. Raji Reddy; Amar G. Chittiboyina; Rajashaker Kache; Jae-Chul Jung; E. Blake Watkins; Mitchell A. Avery

Publisher
John Wiley and Sons
Year
2005
Weight
31 KB
Volume
36
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

๐Ÿ“œ SIMILAR VOLUMES

The diethylisopropylsilyl group: A new p
The diethylisopropylsilyl group: A new protecting group for alcohols
โœ Kazunobu Toshima; Satsuki Mukaiyama; Mitsuhiro Kinoshita; Kuniaki Tatsuta ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 167 KB

The diethylisopropylsilyl (DEIPS) group which is a new protective group for alcohols has been first characterized. DEIPS group can be distinguished from t-butyldimethylsilyl, triethylsilyl, tetrahydropyranyl groups and 2-deoxy glycoside with high selectivity in removing under mild acidic condition,

The sisyl (tris(trimethylsilyl)silyl) gr
The sisyl (tris(trimethylsilyl)silyl) group: A fluoride resistant, photolabile alcohol protecting group
โœ Michael A. Brook; Christine Gottardo; Sonya Balduzzi; Mustafa Mohamed ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 253 KB

The use of the tris(trimethylsilyl)silyl (sisyl) group as a photolabile protecting group for primary and secondary alcohols was demonstrated. Sisyl ethers of a number of alcohols (yields 70-97%) were stable to many synthetic protocols, but could be deprotected using photolysis to give the starting a