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(Diphenyl sulfoxide)dimethyl(η5-pentamethylcyclopentadienyl)rhodium(III)

✍ Scribed by Decken, Andreas ;Michaud, Annie ;Mathiotte, Sophie ;Fontaine, Frédéric-Georges

Book ID
104491462
Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
951 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

Data collection

Bruker P4/SMART 1000 CCD areadetector diffractometer Absorption correction: multi-scan (SADABS; Sheldrick, 1997a) T min = 0.769, T max = 0.957 28282 measured reflections 4963 independent reflections 3473 reflections with I > 2(I) R int = 0.053 Refinement R[F 2 > 2(F 2 )] = 0.039 wR(F 2 ) = 0.099 S = 1.05 4963 reflections

📜 SIMILAR VOLUMES

Tri-μ-chloro-bis­[(η5-penta­methyl­cyclo
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✍ Liu, Lihua ;Zhang, Qian-Feng ;Leung, Wa-Hung 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 167 KB

In the cation of the title compound, [Rh 2 Cl 3 (C 10 H 15 ) 2 ]BF 4 , two Rh( 5 -C 5 Me 5 ) fragments are linked by three bridging Cl atoms. Each rhodium center has a pseudo-octahedral coordination geometry, with a C 5 Me 5 group occupying three positions and three Cl atoms completing the coordinat

Bis(acetonitrile-κN)(η5-pentamethylcyclo
Bis(acetonitrile-κN)(η5-pentamethylcyclopentadienyl)(pyrimidine-κN)rhodium(III) bis(hexafluoridophosphate)
✍ Boyer, Julie L. ;Wilson, Scott R. ;Rauchfuss, Thomas B. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 983 KB

The title compound, [Rh(C 10 H 15 , where Cp\* is pentamethylcyclopentadienyl, was obtained from the treatment of an acetonitrile solution of [Cp\*Rh(NCMe) 3 ](PF 6 ) 2 with an excess of pyrimidine. The Rh III center is coordinated by one Cp\* ring, two acetonitrile ligands and one pyrimidine ligan