In the cation of the title compound, [Rh 2 Cl 3 (C 10 H 15 ) 2 ]BF 4 , two Rh( 5 -C 5 Me 5 ) fragments are linked by three bridging Cl atoms. Each rhodium center has a pseudo-octahedral coordination geometry, with a C 5 Me 5 group occupying three positions and three Cl atoms completing the coordinat
Di-μ-chlorido-bis[chlorido(η5-pentamethylcyclopentadienyl)rhodium(III)] chloroform trisolvate
✍ Scribed by Govindaswamy, Padavattan ;Süss-Fink, Georg ;Therrien, Bruno
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 138 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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The cation of the title compound, [Ir~2~ClH~2~(C~6~H~5~S)~2~(C~48~H~40~P~2~)~2~]Cl·2C~2~H~4~Cl~2~, exists as a bridged bifacial octahedral dinuclear iridium structure with __C__ ~2~ symmetry (Cl lies on the rotation axis). The coordination environment of the Ir atom can be described as highly distor
In the title dinuclear rhodium complex, [(- the terminal trifluoromethanesulfonate ligands adopt a trans configuration with respect to each other and the RhÁ Á ÁRh distances range from 5.5157 (8) to 5.5389 (6) A ˚. There are two and a half molecules within the asymmetric unit, one of the molecules