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Chlorido(η5-penta­methyl­cyclo­penta­dien­yl)(1,10-phenanthroline-κ2N,N′)iridium(III) trifluoro­methane­sulfonate

✍ Scribed by Scharwitz, Michael ;Schäfer, Sven ;Almsick, Tobias van ;Sheldrick, William S.

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
277 KB
Volume
63
Category
Article
ISSN
1600-5368

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✍ Ren, Chun-Xia ;Ding, Yu-Qiang 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 184 KB

The crystal structure of the title complex, [Ir(C 10 H 15 )-(C 4 N 2 S 2 )], is composed of distinct [ 5 -Cp\*Ir(mnt)] (Cp\* is pentamethylcyclopentadienyl and mnt is 1,2-dicyanoethylenedithiolate) molecules separated by normal van der Waals contacts. The asymmetric unit consists of two molecules. T

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In the title structure, [CoRu(C 10 H 20 )Cl(C 17 H 14 P) 2 ]PF 6 Á-0.5CH 2 Cl 2 , the Ru atom is coordinated by a pentamethylcyclopentadienyl ring, one Cl atom and two P atoms of the chelating 1,1 0 -bis(diphenylphosphino)cobaltocenium ligand, giving a three-legged piano-stool geometry. The solvent