✦ LIBER ✦
Di-μ-benzenethiolato-μ-chlorido-bis{hydrido[(S)-(−)-2,2′-bis(di-p-tolylphosphanyl)-1,1′-binaphthyl]iridium(III)} chloride 1,2-dichloroethane disolvate
✍ Scribed by Yamagata, Tsuneaki ;Hoshida, Kazunori ;Iseki, Aika ;Tani, Kazuhide
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 218 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The cation of the title compound, [Ir~2~ClH~2~(C~6~H~5~S)~2~(C~48~H~40~P~2~)~2~]Cl·2C~2~H~4~Cl~2~, exists as a bridged bifacial octahedral dinuclear iridium structure with C
~2~ symmetry (Cl lies on the rotation axis). The coordination environment of the Ir atom can be described as highly distorted octahedral with two P atoms, two bridging phenyl thiolato S atoms, a bridging chloride ligand, and a terminal hydride ligand.