Isocyanide complexes of rhodium, part 41,2). η5-pentamethylcyclopentadienyl-rhodium (III) compounds
✍ Scribed by Jon A. McCleverty; John Williams
- Book ID
- 105176327
- Publisher
- Springer
- Year
- 1978
- Tongue
- English
- Weight
- 354 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0340-4285
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Data collection Bruker P4/SMART 1000 CCD areadetector diffractometer Absorption correction: multi-scan (SADABS; Sheldrick, 1997a) T min = 0.769, T max = 0.957 28282 measured reflections 4963 independent reflections 3473 reflections with I > 2(I) R int = 0.053 Refinement R[F 2 > 2(F 2 )] = 0.039
In the cation of the title compound, [Rh 2 Cl 3 (C 10 H 15 ) 2 ]BF 4 , two Rh( 5 -C 5 Me 5 ) fragments are linked by three bridging Cl atoms. Each rhodium center has a pseudo-octahedral coordination geometry, with a C 5 Me 5 group occupying three positions and three Cl atoms completing the coordinat