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Diazocine chemistry. V. Synthesis and rearrangement of dibenzo[b,f] [1,4]diazocine-6,11(5H,12H)-dione

✍ Scribed by Paudler, William W.; Zeiler, Andrew G.

Book ID
126192550
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
402 KB
Volume
34
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES

4,10-Dibromo-2,8-dimethyl-6H,12H-5,11-me
4,10-Dibromo-2,8-dimethyl-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine
✍ Faroughi, Masoud ;Try, Andrew C. ;Turner, Peter πŸ“‚ Article πŸ“… 2007 πŸ› International Union of Crystallography 🌐 English βš– 284 KB

In the molecule of the title compound, C 17 H 16 Br 2 N 2 , the 4,10bromo-2,8-dimethyl analogue of Tro Β¨ger's base, the two aryl rings are offset with respect to one another by virtue of the diazocine bridge. There are two crystallographically independent molecules in the unit cell and both of these

2,8-Dimethoxy-4,10-dimethyl-1,3,7,9-tetr
2,8-Dimethoxy-4,10-dimethyl-1,3,7,9-tetranitro-6H,12H-5,11-methanodibenzo[b,f][1,5]diazocine
✍ Bhuiyan, M. Delower H. ;Jensen, Paul ;Try, Andrew C. πŸ“‚ Article πŸ“… 2007 πŸ› International Union of Crystallography 🌐 English βš– 488 KB

In the molecule of the title compound, C~19~H~18~N~6~O~10~, the 2,8-dimethoxy-4,10-dimethyl-1,3,7,9-tetranitro analogue of TrΓΆger's base, the diazocine bridge imparts a twist such that the two aryl rings are offset with respect to one another. The hinge angle of the molecule, measured as the dihedra