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Synthesis and Structure of Pentamethylcyclopentadienyl Tungsten(V) Complexes Containing Functionalized 6,12-Epiiminodibenzo[ b , f ][1.5]diazocine Ligands

✍ Scribed by Redshaw, Carl; Wood, Paul T.; Elsegood, Mark R. J.


Book ID
121459849
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
96 KB
Volume
26
Category
Article
ISSN
0276-7333

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Seven 6, [1,51diazocines 2 with different substituents at position 13 have been prepared from o-(triphenylphosphoranylideneamino)benzaldehyde I and the corresponding aliphatic and aromatic primary amines in yields ranging from 40 to 80%. The molecular and crystal structures of componds 2d (R = 4 H3