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Diazido­(1,4,7-tribenzyl-1,4,7-triaza­cyclo­nonane-κ3N)copper(II)

✍ Scribed by Yang, Yong-Sheng ;Gu, Wen ;Qian, Jing ;Gao, Feng-Xian ;Yan, Shi-Ping


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
107 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title compound, [Cu(N 3 ) 2 (C 27 H 33 N 3 )], the copper(II) atom is coordinated by five N atoms from the 1,4,7-tribenzyl-1,4,7-triazacyclononane ligand and the azide ions in a slightly distorted square-pyramidal geometry.


📜 SIMILAR VOLUMES


1,4,7-Triaza­cyclo­nonane hemihydrate
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✍ Klitgaard, Søren Kegnaes ;Magnussen, Magnus 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 99 KB

The structure of the title complex, [CrCl 3 (C 9 H 21 N 3 )], contains a distorted octahedral chromium(III) centre. The facial tridentate N-coordinating 1,4,7-trimethyl-1,4,7-triazacyclononane ligand and three chloride ions make up the first coordination sphere.

Di­chloro­oxo(N,N′,N′′-tri­methyl-1,4,7-
✍ Fiedler, Dorothea ;Miljanić, Ognjen S. ;Welch, Eric J. 📂 Article 📅 2002 🏛 International Union of Crystallography 🌐 English ⚖ 237 KB

In the title compound, [VOCl 2 (C 9 H 21 N 3 )], the V atom is at the center of a distorted octahedral coordination sphere and is coordinated by the three N atoms of the N,N H ,N HH -trimethyl-1,4,7-triazacyclononane (Me 3 tacn) ligand, and by two chlorides and an oxo ligand.