Trichloro(1,4,7-trimethyl-1,4,7-triazacyclononane)chromium(III)
✍ Scribed by Klitgaard, Søren Kegnaes ;Magnussen, Magnus
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 99 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The structure of the title complex, [CrCl 3 (C 9 H 21 N 3 )], contains a distorted octahedral chromium(III) centre. The facial tridentate N-coordinating 1,4,7-trimethyl-1,4,7-triazacyclononane ligand and three chloride ions make up the first coordination sphere.
📜 SIMILAR VOLUMES
The title compound, [La(C 8 H 9 ) 3 (C 9 H 21 N 3 )], incorporating a fac-3 N ligand and formed by reaction of La(CH 2 C 6 H 4 -4-Me) 3 (THF) 3 (THF is tetrahydrofuran) and 1,4,7-trimethyl-1,4,7-triazacyclononane (Me 3 -TACN), was synthesized in THF solution. In the crystal structure, the La atom is
An octahedrally coordinated trialkylyttrium(III): tris(trimethylsilylmethyl)(1,4,7-trimethyl-1,4,7triazacyclononane)yttrium(III)
In the title compound, [Cu(N 3 ) 2 (C 27 H 33 N 3 )], the copper(II) atom is coordinated by five N atoms from the 1,4,7-tribenzyl-1,4,7-triazacyclononane ligand and the azide ions in a slightly distorted square-pyramidal geometry.