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Di­chloro­oxo(N,N′,N′′-tri­methyl-1,4,7-tri­aza­cyclo­nonane-κ3N)­vanadium(IV)

✍ Scribed by Fiedler, Dorothea ;Miljanić, Ognjen S. ;Welch, Eric J.

Publisher
International Union of Crystallography
Year
2002
Tongue
English
Weight
237 KB
Volume
58
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, [VOCl 2 (C 9 H 21 N 3 )], the V atom is at the center of a distorted octahedral coordination sphere and is coordinated by the three N atoms of the N,N H ,N HH -trimethyl-1,4,7-triazacyclononane (Me 3 tacn) ligand, and by two chlorides and an oxo ligand.

📜 SIMILAR VOLUMES

Carbonyl­[1-(2-pyridyl­methyl)-1,4,7-tri
Carbonyl­[1-(2-pyridyl­methyl)-1,4,7-tri­aza­cyclo­nonane-κ4N](tri­phenyl­phosphine)­ruthenium(II) dichloride di­chloro­methane sesquisolvate
✍ Gott, Andrew L. ;McGowan, Patrick C. ;Thornton-Pett, Mark 📂 Article 📅 2003 🏛 International Union of Crystallography 🌐 English ⚖ 252 KB

The title ruthenium±carbonyl complex, [Ru(C 12 H 20 N 4 )-(C 18 H 15 P)(CO)]Cl 2 Á1.5CH 2 Cl 2 , crystallizes in the triclinic space group P1 as a monomeric complex.

Diazido­(1,4,7-tribenzyl-1,4,7-triaza­cy
Diazido­(1,4,7-tribenzyl-1,4,7-triaza­cyclo­nonane-κ3N)copper(II)
✍ Yang, Yong-Sheng ;Gu, Wen ;Qian, Jing ;Gao, Feng-Xian ;Yan, Shi-Ping 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 107 KB

In the title compound, [Cu(N 3 ) 2 (C 27 H 33 N 3 )], the copper(II) atom is coordinated by five N atoms from the 1,4,7-tribenzyl-1,4,7-triazacyclononane ligand and the azide ions in a slightly distorted square-pyramidal geometry.