In the title compound, [Cu(C 6 H 5 O 5 ) 2 (H 2 O) 2 ], the Cu II atom, located on an inversion center, is coordinated by four O atoms from two malate ligands forming the equatorial plane and two water molecules in axial positions, resulting in an elongated octahedral geometry. The structure of this
Diaquabis(malato-κ2O,O′)nickel(II)
✍ Scribed by Liu, Hui-Qin
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 499 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, [Ni(C 6 H 5 O 5 ) 2 (H 2 O) 2 ], the Ni II atom, located on an inversion centre, is coordinated by four O atoms from two malate ligands and two water molecules in an octahedral geometry showing a very large axial distortion. The packing is governed by intermolecular O-HÁ Á ÁO hydrogen bonds.
📜 SIMILAR VOLUMES
In the title complex, diaquabis(2-amino-3-methylbutyrato-2 N,O)nickel(II), [Ni(C 5 H 10 NO 2 ) 2 (H 2 O) 2 ], the Ni II atom (site symmetry 2) is octahedrally coordinated by two N,O-bidenate valinate ions and two water molecules. A network of intermolecular hydrogen bonds links the complex molecules
In the title complex, [Mn(C 8 H 7 O 3 ) 2 (H 2 O) 2 ], the Mn II atom is located on a twofold axis and is coordinated by two vanillinate anions and two water molecules in a distorted octahedral geometry. The vanillinate ligand chelates to the Mn II atom through its methoxy and hydroxy O atoms, with
The title complex, [Co(C 3 H 3 O 4 ) 2 (H 2 O) 2 ], is isostructural with its iron, zinc and magnesium analogues. The molecule has inversion symmetry. The molecules are linked together via O-HÁ Á ÁO hydrogen bonds, leading to a three-dimensional network.